PFAS (Per and Polyfluoroalkyl Substances): PFAS refers to a large group of synthetic chemicals that have been used in various industrial and consumer products since the 1940s for their water and grease-resistant properties. According to the Environmental Protection Agency (EPA), there are thousands of PFAS chemicals found in many different consumer, commercial, and industrial products, making it challenging to study and assess the potential human health and environmental risks.
These chemicals are characterized by their strong carbon-fluorine bonds, which make them highly resistant to breakdown in the environment. As a result, PFAS are often called “forever chemicals” because they don’t break down naturally for extremely long periods of time. The EPA says that PFAS have been released into the environment through industrial manufacturing and the use and disposal of PFAS-containing products contaminating soil, water supplies, and consequently our drinking water.
PFOA and PFOS are two types of PFAS that have been produced in the largest amounts in North America.
PFOA (Perfluorooctanoic Acid): PFOA is one specific type of PFAS. Its chemical structure includes an eight-carbon chain fully fluorinated, with a carboxylate group at the end. This structure gives PFOA its unique properties, such as resistance to water, oil, and heat. PFOA has been widely used in manufacturing non-stick cookware, waterproof clothing, and firefighting foams. Despite its beneficial properties in manufacturing, PFOA is persistent in the environment and the human body, raising significant health concerns. When PFOA contaminates water supplies, it can lead to long-term exposure through drinking water, posing serious health risks.
PFOS (Perfluorooctane Sulfonate): PFOS is another prominent member of the PFAS family. Similar to PFOA, it features a fully fluorinated eight-carbon chain but with a sulfonate group at the end. PFOS has been used extensively in products like stain-resistant fabrics, firefighting foams, and some pesticides. Its chemical stability and resistance to degradation make it a persistent environmental pollutant, posing risks to human health and ecosystems. When PFOS contaminates drinking water sources, it can lead to chronic exposure, significantly impacting human health.
Differences and Common Uses: While PFOA and PFOS are both part of the broader PFAS category and share similar chemical characteristics, their specific functional groups (carboxylate for PFOA and sulfonate for PFOS) influence their applications and environmental behavior. PFOA is primarily associated with products requiring high heat resistance, such as non-stick cookware, while PFOS has been used more in stain repellents and firefighting foams due to its surfactant properties.
Both PFOA and PFOS are persistent and bioaccumulative, meaning they can accumulate in the human body over time and are resistant to natural breakdown processes. This persistence underlines the importance of targeted mitigation strategies to reduce exposure and safeguard public health, especially in residential water supplies.